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Geotechnical and Geological Engineering - Small variation in shear strength parameters results in remarkable changes in the safety factor (SF) of a rock slope. In this regard, rock mass strength of...  相似文献   
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A chelating resin is prepared by condensation polymerization of aniline with formaldehyde and characterized by Fourier transform infrared spectrometer, elemental analysis and thermogravimetric analysis and studied for the preconcentration and determination of trace Molybdate ion from environmental water sample using inductive couple plasma atomic emission spectroscopy. The optimum pH value for sorption of the metal ion was 5. The sorption capacity of functionalized resin is 3.1 mg/g. The chelating sorbent can be reused for 20 cycles of sorption-desorption without any significant change in sorption capacity. The best desorption of the metal ions from resin was obtained by 0.5 mol/L nitric acid as eluting agent. The profile of molybdenum uptake on this sorbent reflects good accessibility of the chelating sites in the aniline-formaldehyde. Scatchard analysis revealed that the homogeneous binding sites were formed in the polymers. The equilibrium adsorption data of Molybdate ion modified resin were analyzed by five isotherm models such as Langmuir, Freundlich and Temkin. Langmuir isotherm parameters obtained from the four Langmuir linear equations by using linear method. Based on the Langmuir isotherm analysis, the monolayer adsorption capacity was determined to be 4.03 mg/g at 20 °C. The method was applied for molybdenum ions determination from river water sample.  相似文献   
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A field study was performed at rivers in Gunung Jerai forest reserve(Kedah,Malaysia) to assess seasonal changes in mayfly community structure and abundance in relation to altitude and water physicochemistry.Rivers at lower(Batu Hampar River) and higher(Teroi River) elevations were visited through dry and wet seasons in September 2007 to August 2008.Monthly visits were made to 20 sites on each river,and water and aquatic insects were sampled using D-pond aquatic nets.Water was warmer,more acid,and more turbid in Teroi River during wet season.Ammonia was the only nutrient exhibiting significant seasonal variations(greater during wet season).Chemical oxygen demand content was higher in Teroi River where biochemical oxygen demand content was low during wet season.Species richness was higher in Batu Hampar River,but displayed seasonal variations only in Teroi River.Among the eight families encountered,Baetidae was the commonest.Baetid abundance was usually high during wet season,and those belonging to the dominant genus(Baetis) were more abundant in Teroi River.Heptageniidae was the second commonest family;its predominant genus,Thalerospyrus was more abundant in Teroi River during dry season.Caenidae,Leptophlebiidae and Oligoneuriidae were only found in Batu Hampar River where their abundances peaked during dry season,i.e.,Habrophlebiodes sp.and Isonychia sp.Ephemerellidae and Teloganodidae occurred only in Teroi River,with the first found only during dry season.Mayflies were recorded under very distinct physicochemical conditions,illustrating their potential usefulness for assessing water quality.Caenids,leptophlebids,oligoneurids ephemerellids and teloganodids seem to be particularly sensitive to temperature,acidity,turbidity,chemical oxygen demand and biochemical oxygen demand,parameters that varied with river altitude.  相似文献   
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In regional exploration programs, the distribution of elements in known mineral deposits can be used as a guide for the classification of deposits, search for new prospects and modeling ore deposit patterns. The Sanandaj–Sirjan Zone (SSZ) is a major metallogenic zone in Iran, containing lead and zinc, iron, gold, copper deposits. In the central part of the SSZ, lead and zinc mineralization is widespread and hitherto exploration has been based on geological criteria. In this study, we used clustering techniques applied to element distribution for classification lead and zinc deposits in the central part of the SSZ. The hierarchical clustering technique was used to characterize the elemental pattern. Elements associated with lead and zinc deposits were separated into four clusters, encompassing both ore elements and their host rock-forming elements. It is shown that lead and zinc deposits in the central SSZ belong to two genetic groups: a MVT type hosted by limestone and dolomites and a SEDEX type hosted by shale, volcanic rocks and sandstone. The results of elemental clustering were used for pattern recognition by the K-means method and the respective deposits were classified into four distinct categories. K-means clustering also reveals that the elemental associations and spatial distribution of the lead and zinc deposits exhibit zoning in the central part of the SSZ. The ratios of ore-forming elements (Sb, Cd, and Zn) vs. (Pb and Ag) show zoning along an E–W trend, while host rock-forming elements (Mn, Ca, and Mg) vs. (Ba and Sr) show a zoning along a SE–NW trend. Large and medium deposits occur mainly in the center of the studied area, which justify further exploration around occurrences and abandoned mines in this area. The application of a pattern recognition method based on geochemical data from known mineralization in the central SSZ, and the classification derived from it, uncover elemental zoning, identify key elemental associations for further geochemical exploration and the potential to discover possible target areas for large to medium size ore deposits. This methodology can be applied in a similar way to search for new ore deposits in a wide range of known metallogenic zones.  相似文献   
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The applicability of three kinds of electrode configurations used to delineate a buried horizontal pipe was studied. A 3D resistivity imaging survey was carried out along eight parallel lines using pole-pole, pole-dipole, and dipole-dipole arrays with 1m minimum electrode spacings. Roll-along measurements were carried out to cover a rectangular grid. The 2D and 3D least squares algorithms based on the robust inversion method were used in the inversion of the apparent resistivity data sets. The 2D inversion of data sets could not delineate the orientation and dimension of the subsurface anomalies clearly. To obtain more accurate results, a 3D joint inversion of the pole-pole and pole-dipole data sets was performed, as well as of pole-pole and dipole-dipole data sets. In this case, both horizontal and vertical dimensions of subsurface structures were resolved. The resulting model obtained from each array was compared to those of joint inversion method. The result showed that the horizontal resolution does not improve so much as that in the vertical direction when joint inversion is applied.  相似文献   
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Four bacterial isolates (two resistant and two sensitive to chromium) were isolated from soil contaminated with tannery effluents at Jajmau (Kanpur), India, and were identified by 16S rDNA gene sequencing as Stenotrophomonas maltophilia, Exiguobacterium sp., Pantoea sp., and Aeromonas sp. Biosorption of chromium by dried and living biomasses was determined in the resistant and sensitive isolates. The effect of pH, initial metal concentration, and contact time on biosorption was studied. At pH 2.5 the living biomass of chromium resistant isolate Exiguobacterium sp. ZM‐2 biosorbed maximum amount of Cr6+ (29.8 mg/g) whereas the dried biomass of this isolate biosorbed 20.1 mg/g at an initial concentration of 100 mg/L. In case of chromate sensitive isolates, much difference was not observed in biosorption capacities between their dried and living biomasses. The maximum biosorption of Cr3+ was observed at pH 4.5. However, biosorption was identical in resistant and sensitive isolates. The data on chromium biosorption were analyzed using Langmuir and Freundlich isotherm model. The biosorption data of Cr6+ and Cr3+ from aqueous solution were better fitted in Langmuir isotherm model compared to Freundlich isotherm model. Metal recovery through desorption was observed better with dried biomasses compared to the living biomasses for both types of chromium ions. Bioaccumulation of chromate was found higher in chromate resistant isolates compared to the chromate sensitive isolates. Transmission electron microscopy confirmed the accumulation of chromium in cytoplasm in the resistant isolates.  相似文献   
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Drought analysis in Jordan under current and future climates   总被引:2,自引:0,他引:2  
Droughts have adverse socioeconomic, agricultural, and environmental impacts that can be reduced by assessing and forecasting drought behavior. The paper presents detailed analyses of both meteorological and vegetative droughts over the period from 1970 to 2005. Standardized Precipitation Index (SPI) and Normalized Difference Vegetation Index (NDVI) have been used to quantify drought according to severity, magnitude and spatial distribution at the Hashemite Kingdom of Jordan. Results suggest that the country faced during the past 35 years frequent non-uniform drought periods in an irregular repetitive manner. Drought severity, magnitudes and life span increased with time from normal to extreme levels especially at last decade reaching magnitudes of more than 4. Generated NDVI maps spatial analyses estimate crop-area percentage damage due to severe and extremely severe drought events occurred during October, December, and February of 2000 to be about 10%, 45%, and 30%, respectively. In response to drought spatial extent, the paper suggest the presence of two drought types, local drought acting on one or more geographical climatic parts and national drought, of less common but more severe, that extend over the whole country. Droughts in Jordan act intensively during January, February and March and tend to shift position with time by alternative migrations from southern desert parts to northern desert parts and from the eastern desert parts to highlands and Jordan Rift Valley (JRV) at the west. The paper also investigates the potential use of Global Climate Model’s (GCM) to forecast future drought events from 2010 till 2040. Tukey HSD test indicates that ECHAM5OM GCM is capable to predicted rainfall variation at the country and suggests future droughts to become more intensive at the northern and southern desserts with 15% rainfall reduction factor, followed by 10% reduction at the JRV, and 5% at the highlands.  相似文献   
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